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Novel Reduction of Ketones by Diphenylsilane

✍ Scribed by GILMAN, HENRY; DIEHL, JUSTIN

Book ID
126451534
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
543 KB
Volume
26
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

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Rhodium-catalyzed reduction of esters to alcohols using diphenylsilane
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Carboxylic esters were reduced to alcohols by diphenylsilane catalyzed by a Rh complex at room temperature. For example, ethyl decanoate and ethyl phenylacetate were converted to decanol and 2-phenylethanol by [RhCl(cod)]2 / 4PPh3 for 72 hours in 98 and 92% yields, respectively. Wilkinson's catalyst