## Reaction of a 3-oxazolininyM-hydroxymethylazetidin-2-one with excess NaOh4e in rejluzing methanol gives the corresponding I-oxa-,8-diazabicyclo[4.3.0]nonan-5,9-dione stereospecifcally in nearly quantitative yield via a novel skeletal rearrangement, which includes a gamnu-l&one as a key-intermedia
Novel Rearrangements of 4-Silyl-3-buten-2-ones.
โ Scribed by Michael E. Jung; Grazia Piizzi
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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