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Novel reactions of 1-benzoyl-2-methyl-3,4-dihydro-2-thianaphthalene with compounds having an acidic hydrogen

โœ Scribed by Mikio Hori; Tadashi Kataoka; Hiroshi Shimizu; Eiji Imai; Akihiko Tomoto


Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
207 KB
Volume
23
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Thermal reaction of l-benzoyl-2-methyl-3,4-dihydro-2-thianaphthalene(l)

or thiols in benzene afforded ring-opened products cleaving C -S bona. On the other hand, ring-expanded product was produced by the reaction of11 with imides or phenols.


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Syntheses and thermal reactions of 2-alk
โœ Mikio Hori; Tadashi Kataoka; Hiroshi Shimizu; Akihiko Tomoto ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 266 KB

1-Benzoyl-2-methyl-3,4-dihydro-2-thianaphthalene (4a) underwent novel intermolecular 1,4-rearrangement in refluxing toluene to give an enol ether 5z while rearrangement of 2-phenyl derivative 4e proceeded intramolecularly in refluxing xylene to afford a 1,4-rearranged enol ether 5b. 5 the other hand