1-Benzoyl-2-methyl-3,4-dihydro-2-thianaphthalene (4a) underwent novel intermolecular 1,4-rearrangement in refluxing toluene to give an enol ether 5z while rearrangement of 2-phenyl derivative 4e proceeded intramolecularly in refluxing xylene to afford a 1,4-rearranged enol ether 5b. 5 the other hand
โฆ LIBER โฆ
Novel reactions of 1-benzoyl-2-methyl-3,4-dihydro-2-thianaphthalene with compounds having an acidic hydrogen
โ Scribed by Mikio Hori; Tadashi Kataoka; Hiroshi Shimizu; Eiji Imai; Akihiko Tomoto
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 207 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
Thermal reaction of l-benzoyl-2-methyl-3,4-dihydro-2-thianaphthalene(l)
or thiols in benzene afforded ring-opened products cleaving C -S bona. On the other hand, ring-expanded product was produced by the reaction of11 with imides or phenols.
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