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Novel Reaction of Complex Salts [(μ-RE)(μ-CO)Fe 2 (CO) 6 ][HNEt 3 ] (E = S, Se) with Phosphaalkene t-Bu(Me 3 SiO)CPSiMe 3 . Synthesis and Spectroscopic and Crystallographic Characterization of Butterfly Fe 2 EP Clusters (μ-RE)[μ-t-Bu(Me 3 SiO)CHPH]Fe 2 (CO) 6 (E = S, Se)

✍ Scribed by Song, Li-Cheng; Lu, Guo-Liang; Hu, Qing-Mei; Sun, Jie-


Book ID
127043950
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
196 KB
Volume
18
Category
Article
ISSN
0276-7333

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The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.