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Novel radiolytic species in aqueous potassium bromide solutions as studied by pulse radiolysis

✍ Scribed by B. Čerček

Publisher
Elsevier Science
Year
1972
Weight
389 KB
Volume
4
Category
Article
ISSN
0020-7055

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✍ Haim Levanon; P. Neta 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 356 KB

Formation of cation radicals by pulse radiolysis of metalloporphyrins and chlorophyll a in 1,2dichIoroethane is reported. Demetalation of the metalloporphyrin by radiolytically produced HCl is also observed. Rate constants for demetalation of ZnTPP and Chl a are 1 .I X IO8 and = 3 X IO8 h!-' s-I\_ O