Novel porphyrin-grafted poly(phenylene vinylene) derivatives: Synthesis and photovoltaic properties
✍ Scribed by Jichang Feng; Qinghui Zhang; Wang Li; Yang Li; Mujie Yang; Yong Cao
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 335 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0021-8995
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## Abstract Two novel phenyl‐substituted poly(__p__‐phenylene vinylene) derivatives, poly{2‐[3′,4′‐(2″‐ethylhexyloxy)(3″,7″‐dimethyloctyloxy)benzene]‐1,4‐phenylenevinylene} (EDP‐PPV) and poly{2‐[3′,4′‐(2″‐ethylhexyloxy)(3″,7″‐dimethyloctyloxy)benzene]‐5‐methoxy‐1,4‐phenylenevinylene} (EDMP‐PPV), an
## Abstract Three alternating conjugated copolymers of cyanosubstituted poly(__p__‐phenylene vinylene) (CN–PPV) with phenylene ethynylene and thienylene vinylene moieties, **P1, P2,** and **P3,** were synthesized via cross‐coupling polycondensation with Pd(PPh~3~)~2~Cl~2~ as a catalyst. Their struc