Novel poly(diphenylacetylene)s with both alkyl and silyl groups as gas permeable membranes: Synthesis, desilylation, and gas permeability

✍ Scribed by Aiko Takeda; Toshikazu Sakaguchi; Tamotsu Hashimoto

• Publisher: Elsevier Science
• Year: 2010
• Tongue: English
• Weight: 417 KB
• Volume: 51
• Category: Article
• ISSN: 0032-3861
• DOI: 10.1016/j.polymer.2010.01.022

✦ Synopsis

Diphenylacetylenes having a dimethyloctylsilyl group and an alkyl group at para positions [Me 2 n-C 8 H 17 SiC 6 H 4 C^CC 6 H 4 R; R ¼ H (1a), i-Pr (1b), t-Bu (1c), n-Bu (1d)] and having only an alkyl group [PhC^CC 6 H 4 R; R ¼ i-Pr (1B), t-Bu (1C)] were synthesized and then polymerized with TaCl 5 /n-Bu 4 Sn catalyst to provide the corresponding poly(diphenylacetylene)s (2a, 2b, 2c, 2d, 2B, and 2C). The formed polymers afforded tough free-standing membranes by casting from toluene solutions. Desilylation reaction of Si-containing membranes (2a-d) was carried out with trifluoroacetic acid to give the desilylated membranes (3a-d). The permeability of these membranes to O 2 , N 2 , and CO 2 were determined. All the Sicontaining membranes exhibited almost the same gas permeability. The desilylation of Si-containing membranes of 2a-c resulted in large increase of gas permeability. No apparent increasing of gas permeability was observed in the desilylation of 2d. To clarify the effects of desilylation, CO 2 diffusivity (D(CO 2 )), CO 2 solubility (S(CO 2 )), and fractional free volume (FFV) of the polymer membranes were investigated. The S(CO 2 ) values of desilylated membranes were much larger than that of Si-containing counterparts. The D(CO 2 ) and FFV of membranes of 2a-c increased through desilylation. The desilylated membrane of 3d had small D(CO 2 ) value and almost the same FFV compared with 2d. Further, the comparison of the permeability between three types of membranes with the same chemical structure revealed that the microvoids were not generated by the desilylation of membranes of poly(diphenylacetylene)s containing alkyl groups.