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Novel poly(arylene vinylene)s carrying donor and acceptor substituents

✍ Scribed by Andrew C. Grimsdale; Franco Cacialli; Johannes Grüner; Xiao-Chang Li; Andrew B. Holmes; Stephen C. Moratti; Richard H. Friend

Book ID
116136791
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
260 KB
Volume
76
Category
Article
ISSN
0379-6779

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We investigate theoretically the influence of substitution by various donor and acceptor groups onto the phenyl rings and/or the vinylene units of poly(paraphenylene vinylene) and poly(paraphenylene). Using quantum chemical methods, we calculate the magnitudes of the forbidden energy gaps, the ioniz