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Novel Platinum Complexes Enable Selective C-H and C-Si Activation of Tetramethylsilane at Room Temperature

✍ Scribed by Prof. Dr. Peter Hofmann; Dipl.-Chem. Helmut Heiss; Dipl.-Chem. Peter Neiteler; Prof. Dr. Gerhard Müller; Dipl.-Chem. Joachim Lachmann

Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
475 KB
Volume
29
Category
Article
ISSN
0044-8249

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✦ Synopsis

Dedicated to Professor Paul von RaguC Schleyer on the occasion of his 60th birthday

The intermolecular activation of C-H and C-X bonds at saturated carbon [Eq. (a)] is one of the topical fields of research in organometallic chemistry."] Since 1982, a series of transition metal complex fragments ML, have been reported, which can be generated in solution, and which are capable of intermolecular homogeneous C-H activation even at saturated (sp3) C atoms.

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