Novel photooxidation of alkenes sensitized by p-dimethoxybenzene
โ Scribed by Uday T. Bhalerao; Madabhushi Sridhar
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- French
- Weight
- 133 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
Photoexcited p-dimethoxybenzene catalyses oxidative cleavage of various alkenes to corresponding carbonyls in the presence of oxygen.
๐ SIMILAR VOLUMES
The oxidation of isoeugenol to a variety of canpow& is well docwnented in the literature (l-5). We have extended this research by examining the effect of dye-sensitized photooxidation on isoeugenol (I), a mananer that has been ifirplicated in the biosynthesis of lignin (6). I Isolation of \*llignol
## Abstract For Abstract see ChemInform Abstract in Full Text.
In a previous investigation1 we have reported that the dye-sensitized photwxidation of [2.21 (2.5)furanophane (I) in methanol leads to an oxygenated intermediate which underqoes an 2 intramolecular Diels-Alder reaction forming the diketone (II) . We have now observed that this oxidation reaction ta