✦ LIBER ✦
Novel photoisomerization of 9-tert-butyl-10-cyanoanthracene involving 1,2-transfer of methyl group
✍ Scribed by Ji-ben Meng; Xinkan Yao; Honggen Wing; Teruo Matsuura; Yoshikatsu lto
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 289 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
✦ Synopsis
A novel photoisomeriaation of 9-tert-butyl-lo-cyanoaathracene Q) involving the 1,2-transfer of a methyl group ia described. Irradiation of 1 in acetonitrile at -20°C gave a dibeusobornadiene 2 as the sole isolable product. The structure of pvaa established by X-ray crystallography. In the solid state 1 vas inert to irradiation.