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Novel photoisomerization of 1-acylindoles to 3-acylindolenines. General entry to the total synthesis of Strychnos and Aspidosperma alkaloids

✍ Scribed by Ban, Yoshio; Yoshida, Kiyoshi; Goto, Jiro; Oishi, Takeshi


Book ID
115492514
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
387 KB
Volume
103
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


Studies on the synthesis of strychnos in
✍ Mercedes Alvarez; Rodolfo Lavilla; Joan Bosch πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 279 KB

A short, new route to the title tetracyclic substructure of Sf/cycho4 alkaloids, consisting in the nucleophilic attack of an ester a-anion to a pyridinium salt, acid-induced cyclization of the resultant 1,4\_dihydropyridine, and stereospecific elaboration of the ethylidene substituent, is reported.

A General Synthetic Entry to Strychnos A