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Novel photochromic macrocycles composed of thiophene and ethylene building blocks: synthesis, structure, and photochromic property

โœ Scribed by Jun Yin; Yan Lin; Xiufang Cao; Guang-Ao Yu; Sheng Hua Liu


Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
288 KB
Volume
49
Category
Article
ISSN
0040-4039

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Enantiomerically pure and racemic forms of calixsalen-type macrocycles 1 and 2 were synthesized and their crystal structures were determined. The enantiomerically pure crystals of (S,S,S,S,S,S)-1 exhibited thermally reversible photochromism from yellow to orange-red upon photoirradiation in the soli