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Novel photochemical reactions of 1- and 2-naphthols with ethylene promoted by aluminum halides

โœ Scribed by Kakiuchi, Kiyomi; Yamaguchi, Bunji; Kinugawa, Masahiko; Ue, Masaki; Tobe, Yoshito; Odaira, Yoshinobu


Book ID
111933119
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
889 KB
Volume
58
Category
Article
ISSN
0022-3263

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A novel synthesis of spiro[2.6]nonadieno
โœ Tsuyoshi Satoh; Shinobu Nagamoto; Masanobu Yajima; Yukie Yamada; Yuki Ohata; Mak ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 281 KB

## a b s t r a c t The sulfoxide-magnesium exchange reaction of aryl 1-chlorocyclopropyl sulfoxides with i-PrMgCl in THF at low temperature gave magnesium cyclopropylidenes. Treatment of the magnesium cyclopropylidenes with lithium naphtholates or phenolates resulted in the formation of spiro[2.6]n