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Novel Phenanthroline Ligands and Their Kinetically Locked Copper(I) Complexes with Unexpected Photophysical Properties

✍ Scribed by Kalsani, Venkateshwarlu; Schmittel, Michael; Listorti, Andrea; Accorsi, Gianluca; Armaroli, Nicola

Book ID: 125960068
Publisher: American Chemical Society
Year: 2006
Tongue: English
Weight: 126 KB
Volume: 45
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic051828v

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## Abstract A series of copper(II) and copper(I) complexes, [CuX~2~L] (1–6) and [CuL~2~](CuX~2~) (7–12) (X = Cl, Br; L = 2‐R‐9‐R′‐1,10‐phenanthroline, dpp: R = R′ = Ph; npp: R = naphthyl, R′ = Ph; dnp: R = R′ = naphthyl) were synthesized and characterized by elemental analysis, UV/Vis and IR spectr