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Novel Palladium(0)-Catalyzed Coupling Reaction of Dialkoxyborane with Aryl Halides: Convenient Synthetic Route to Arylboronates

✍ Scribed by Murata, Miki; Watanabe, Shinji; Masuda, Yuzuru


Book ID
118036700
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
67 KB
Volume
62
Category
Article
ISSN
0022-3263

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Synthesis of arylboronates via the palla
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The cross-coupling reaction of (RO)2BB(OR)2 (XO = methoxo and pinacolato) with aryl triflates to give arylboronates was carried out at 80 \*C. in the presence of PdCl2(dppf) (3 tool%), dppf (3 tool%) and KOAc (3 equivs) in dioxane. The reaction was available wim various functional groups such as nit