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Novel oxovanadium(iv) heterochelate complexes: synthesis, structure, ESR spectra, and photoluminescence properties

✍ Scribed by E. S. Bazhina, M. E. Nikiforova, G. G. Aleksandrov…

Book ID
120768431
Publisher
Springer
Year
2012
Tongue
English
Weight
477 KB
Volume
61
Category
Article
ISSN
1573-9171

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The aminoalcohol ligands diethanolamine (H 2 dea) and triethanolamine (H 3 tea) react with [VO(acac) 2 ] to yield the tetranuclear oxovanadium(IV) complexes [{VO(dea)} 2 -{VO(acac)} 2 (µ 2 -OMe) 2 ] (1) and [{VO(Htea)} 2 {VO(acac)} 2 (µ 2 -OMe) 2 ] (2). In the case of the potentially bridging aminoa