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Novel oxidative nitrogen to carbon rearrangement found in the conversion of anilines to benzaldoximes by treating with HCHO/H2O2

✍ Scribed by Naval Kapuriya; Kalpana Kapuriya; Narsinh M. Dodia; Yi-Wen Lin; Rajesh Kakadiya; Chao-Ting Wu; Ching-Huang Chen; Yogesh Naliapara; Tsann-Long Su

Book ID
104095201
Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
119 KB
Volume
49
Category
Article
ISSN
0040-4039

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✦ Synopsis

Novel rearrangement was found by reacting anilines with HCHO/H 2 O 2 resulting in the synthesis of various benzaldoximes. The mechanism of the rearrangement is proposed and suggested that the rearrangement might proceed via unstable N-phenyloxazirane intermediate followed by the transfer of aryl moiety from nitrogen to carbon atom leading to the formation of benzaldoxime.

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ChemInform Abstract: Novel Oxidative Nit
ChemInform Abstract: Novel Oxidative Nitrogen to Carbon Rearrangement Found in the Conversion of Anilines to Benzaldoximes by Treating with HCHO/H2O2.
✍ Naval Kapuriya; Kalpana Kapuriya; Narsinh M. Dodia; Yi-Wen Lin; Rajesh Kakadiya; πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 1 views

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