Novel oxidants for polymerization and crystallization of aniline
✍ Scribed by Narendra V. Bhat; Devender T. Seshadri
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 196 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0021-8995
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## Abstract Poly(2‐fluroaniline) and poly(2‐chloroaniline) were synthesized by an electrochemical method in an acetonitrile solution containing tetrabutylammonium perchlorate and perchloric acid. Also, the electrochemical copolymerization of aniline with 2‐fluroaniline and 2‐chloroaniline was carri
## Abstract Potassium iodate–initiated polymerization of aniline was carried out in an acidified aqueous medium in the presence and in the absence of sodium thiosulfate salt. The nature of the polyaniline (PANI) produced depended on the aniline/potassium iodate (A/PI) mole ratio. Green emeraldine s
The oxidative polymerization of aniline in aqueous acidic solution was carried out in the presence of a variety of organic compounds as potential traps for postulated intermediates. The polymerization was inhibited by hindered phenols and electron-rich alkenes, traps for cation-radicals. However, po