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Novel Organometallic Derivatives of Thioesters of the Trivalent Phosphorus Acids: Synthesis and Structure

✍ Scribed by Vasily A Milyukov; Alexander V. Zverev; Sergey M. Podlesnov; Dmitry B. Krivolapov; Igor A. Litvinov; Aidar T. Gubaidullin; Olga N. Kataeva; Allan G. Ginzburg; Oleg G. Sinyashin

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
288 KB
Volume
2000
Category
Article
ISSN
1434-1948

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✦ Synopsis

tricymantrenyl trithiophosphite adopts an unusual asymmetric cis, gauche, trans conformation along the P-S bonds with Thioesters of the phosphorous acid containing cymantrenyl and ferrocenyl substituents at sulfur were obtained for the respect to the phosphorus lone electron pair. Tri-ferrocenyl trithiophosphate possesses a classical propeller-like structure first time from the reaction of organometallic disulfides with white phosphorus. According to an X-ray diffraction study in the solid state which is different from its oxygen analogue.

ing to the class of organometallic thioesters of the trivalent [a]

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also reflected in redox potentials. The furochlorophin 1 b oxidizes to its li cation radical at 0.47 V and reduces at -1.25 V to the anion radical (determined by cyclic voltammetry. versus Ag/AgCl, in CH,CI,). In comparison with etiochlorin I,1121 1 b is easier to oxidize as well as to reduce by abo