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Novel N → C acyl migration reaction of acyclic imides: A facile method for α-aminoketones and β-aminoalcohols

✍ Scribed by Osamu Hara; Masao Ito; Yasumasa Hamada

Book ID: 104259565
Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 236 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01093-4

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✦ Synopsis

The acyclic imides derived from primary benzylic amines and amino acid esters easily undergo the novel N~C acyl migration reaction via a base-generated carbanion, yielding the corresponding o~-aminoketones which are expedient precursors for 13-aminoalcohols.

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