Electrospray ionization mass spectrometry (ESIMS) was used to study the weak non-covalent interactions occurring between 6-bromo-3-(hydroxymethyl)-8-(methylamino)imidazo [ 1,2-a ] pyrazine (1) and calmodulin. The formation of a 2 : 1 (ligand : protein) complex was observed. Using 2, a (diazomethyl)c
✦ LIBER ✦
Novel Mo(V)-Dithiolene Compounds: Characterization of Nonsymmetric Dithiolene Complexes by Electrospray Ionization Mass Spectrometry
✍ Scribed by Dessapt, Rémi; Simonnet-Jégat, Corine; Mallard, Alain; Lavanant, Hélène; Marrot, Jérôme; Sécheresse, Francis
- Book ID
- 121858203
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 159 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0020-1669
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## Abstract When an intramolecular cavity exists in a molecule, it can trap another chemical species to form a host–guest complex. We examine the formation of such an inclusion complex with cucurbit[__n__]uril (CBn, __n__ = 6, 7) as the host to trap alkali metal or ammonium ions as the guest, by el