Novel lead tetraacetate oxidation of longicycline: formation and reactions of the elusive true longicamphor
✍ Scribed by S.N. Suryawanshi; U.R. Nayak
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 120 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
The lead tetraacetate (LTA) oxidation of saturated alcohols in non-polar solvents affords usually as major products unsubstituted tetrahydrofuran-type ethers, the formation of which involves intramolecular 1,5-hydrogen abstraction by the initially produced alkoxy radicals, followed by internal attac
## Abstract Oxidation of 7,8‐diaminotheophylline (1) with lead tetraacetate in refluxing toluene gave a mixture of 3‐amino‐5,7‐dimethylpyrimido[4,5‐__e__][1,2,4]triazine‐6,8‐dione (**2**) and 6‐cyanoimino‐5‐diazo‐1,3‐dimethylpyrimidine‐2,4‐dione (**4**). The latter was transformed to **2** by the r
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