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Novel initiating systems based on nickel phosphine complexes

✍ Scribed by D. F. Grishin; N. B. Valetova; I. S. Il’ichev; M. G. Prokhorova; I. P. Beletskaya

Book ID
106520315
Publisher
Springer
Year
2006
Tongue
English
Weight
285 KB
Volume
55
Category
Article
ISSN
1573-9171

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## Abstract The use of a photocatalyst (tris(2‐phenylpyridine)iridium [Ir(ppy)~3~]) being able to generate both radicals and cations to initiate free radical polymerization and ring opening polymerization is presented. Remarkably, under soft irradiations (fluorescence bulb, sunlight), excellent cat