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Novel head-to-tail alkyl-alkene or alkene-alkene coupling via zirconium-catalyzed reaction of alkylmagnesium derivatives with monosubstituted alkenes

โœ Scribed by Christophe J. Rousset; Ei-ichi Negishi; Noriyuki Suzuki; Tamotsu Takahashi


Book ID
103405017
Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
238 KB
Volume
33
Category
Article
ISSN
0040-4039

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A stereoselective route to alkenyl sulfi
โœ Yukio Hoshino; Tatsuo Ishiyama; Norio Miyaura; Akira Suzuki ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 247 KB

The reaction of 9-alkyl-9-BBNs with 1-bromo-i-phenylthioethene or (E)-and (Z)-2-bromo-lphenylthio-1-alkenes takes place readily in the presence of Pd(PPh& and sodium hydroxide to afford stereodefmed vinylic sulfides in excellent yields.