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Novel Halogenochalcogeno(IV) Acids: [H3O(Benzo-18-crown-6)]2 [Te2Br10] and [H5O2(Dibenzo-24-crown-8)]2 [Te2Br10].

✍ Scribed by A. Hammerschmidt; S. Bonmann; M. Laege; B. Krebs


Publisher
John Wiley and Sons
Year
2005
Weight
17 KB
Volume
36
Category
Article
ISSN
0931-7597

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[H3O Β· (Dibenzo-18-crown-6)][Te2Br9] and
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Red crystals of [H 3 O Β΄(dibenzo-18-crown-6)][Te 2 Br 9 ] (1) were isolated from a solution of TeBr 4 and dibenzo-18crown-6 in CH 3 CN containing a small amount of hydrobromic acid. The compound crystallizes in the triclinic space group P 1 with the cell dimensions a = 9.010(2), b = 13.403(3), c = 1