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Novel, general synthesis of the chiral catalysts diphosphine-ruthenium (II) diallyl complexes and a new practical in situ preparation of chiral ruthenium (II) catalysts

✍ Scribed by J.P. Genêt; C. Pinel; V. Ratovelomanana-Vidal; S. Mallart; X. Pfister; M.C.Caño De Andrade; J.A. Laffitte


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
674 KB
Volume
5
Category
Article
ISSN
0957-4166

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Chiral Half-Sandwich Ruthenium(II) Compl
✍ Daniel Carmona; M. Pilar Lamata; Fernando Viguri; Joaquina Ferrer; Néstor García 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 253 KB 👁 1 views

## Abstract Ruthenium complexes of formula [(η^6^‐arene)Ru(LL\*)(H~2~O)][SbF~6~]~2~ (arene = C~6~H~6~, __p__‐MeC~6~H~4~__i__Pr, C~6~Me~6~; LL\* = bidentate chelate chiral ligand with PN, PP or NN donor atoms) have been tested as catalyst precursors for the asymmetric 1,3‐dipolar cycloaddition of ni