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Novel functional polymers: Poly(dimethylsiloxane)–polyamide multiblock copolymer. III. Synthesis and surface properties of disiloxane–aromatic polyamide multiblock copolymer

✍ Scribed by Tsutomu Furuzono; Koji Seki; Akio Kishida; Taka-Aki Ohshige; Kazunori Waki; Ikuro Maruyama; Mitsuru Akashi

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
1002 KB
Volume
59
Category
Article
ISSN
0021-8995

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✦ Synopsis

Disiloxane-aromatic polyamide (aramid) multiblock copolymers (2SiPASs) were synthesized using 1,3-bis(3-aminopropyl)-l,l,3,3-tetramethyldisiloxane (BATS) as an analog of aramidsilicone resin consisting of aromatic polyamide and poly(dimethylsi1oxane) (PDMS). 2SiPASs afford a transparent and toughened plastic film. The surface properties of 2SiPAS were investigated by X-ray photoelectron spectroscopy (xps) and static contact angle measurement. The results of surface analysis suggested that BATS content of the PSiPAS surface increased with increasing BATS content in bulk. The interaction between the platelets and the 2SiPAS surface was found to be very weak when the BATS content reached 26 wt % in bulk.

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