Novel free radical ring-forming reaction of dichlorocyclobutanones and sequential ring expansion
β Scribed by Dowd, Paul; Zhang, Wei
- Book ID
- 125959412
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 298 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Free radical initiated ring expansion of twelve-, thirteen-, and fourteen-membered carbocyclic rings is described together with a new synthesis of (R)-(-)-muscone. Free radical-initiated ring expansion affords entry to medium-ring carbocycles and heterocycles otherwise difficultly obtained 1ZJ The
Free radical ring-expansion of a variety of heterocycles is described. The regioselective, free radical ring-expansion of P-keto esters1p2r3 has broad potential applicability in organic synthesis. 4 The synthetic utility of the ring-expansion reaction will be further enhanced by the inclusion of he