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Novel Ferrocene Derivatives with PH-Functionalized Phosphanylalkylcyclopentadienyl Ligands: Syntheses and Molecular Structures of rac-[Fe{(η5-C5H4)CMe2PHR}2] (R = Ph, Mes) and rac-[Fe{(η5-C5H4)CMe2PHPh(Cp*TaCl4)}2]

✍ Scribed by Thomas Höcher; Steffen Blaurock; Evamarie Hey-Hawkins


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
348 KB
Volume
2002
Category
Article
ISSN
1434-1948

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✦ Synopsis


Metallocenes / P ligands /


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Organometallic Niobium and Tantalum Comp
✍ Steffen Blaurock; Evamarie Hey-Hawkins 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 173 KB 👁 1 views

The reaction of [Cp\*MCl 4 ] (M ϭ Nb, Ta; Cp\* ϭ C 5 Me 5 ) with PH 2 R in toluene at room temperature gives the primary phosphine complexes [Cp\*MCl 4 (PH 2 R)] [Cp\* ϭ C 5 Me 5 ; M ϭ Nb: R ϭ Bu t (1a), Ad (2a), Cy (3a), Ph (4a), 2,4,6-Me 3 C 6 H 2 (Mes) (5a); M ϭ Ta: R ϭ Bu t (1b), Ad (2b), Cy (3b

P−H-Functionalized Phosphanyl Alcohols: