✦ LIBER ✦

Novel differences between the solid state and solution phase photochemistry of 1,2-cyclodecanedione

✍ Scribed by Gunnar Olovsson; John R. Scheffer; James Trotter; Chung-Hsi Wu

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 198 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)01657-2

No coin nor oath required. For personal study only.

✦ Synopsis

1,2-Cyclodeeanedione (1) undergoes a novel photore.axrangement in the crystalline state that is different from the Norrish/Yang type II photocycl~!ion process observed in solution. A possible mechanism is presented arid discussed. @ 1997 Elsevier Science Ltd.

Medium sized ring and macrocyelic diketones in which the carbonyl groups are separated by an equal number of methylene groups on either side (so-called diametric diketones) display a rich Norrish/Yang type n photocherrdstry that is strongly dependent upon the naxlinm in which the photolyses are carried out. I In the

📜 SIMILAR VOLUMES

ChemInform Abstract: Novel Differences B

ChemInform Abstract: Novel Differences Between the Solid State and Solution Phase Photochemistry of 1,2-Cyclodecanedione.

✍ G. OLOVSSON; J. R. SCHEFFER; J. TROTTER; C.-H. WU 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

The novel solid state and solution phase

The novel solid state and solution phase photochemistry of dimethyl 9-chloromethyl-9,10-dihydro-9,10-ethenoanthracene-11,12-dicarboxylate

✍ Jianxin Chen; Phani Raj Pokkuluri; John R. Scheffer; James Trotter 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 479 KB

Solid-state photochemistry of the mixed

Solid-state photochemistry of the mixed crystals between benzoquinones and polymethylbenzenes

✍ Hideko Koshima; Yosuke Chisaka; Yang Wang; Xinkan Yao; Honggen Wang; Ruji Wang; 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 819 KB

Differences Between Gas-Phase and Solid-

Differences Between Gas-Phase and Solid-State Molecular Structures of the Simplest Phosphonium Ylide, Me3P=CH2

✍ Norbert W. Mitzel; Daniel H. Brown; Simon Parsons; Paul T. Brain; Colin R. Pulha 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 109 KB 👁 2 views

H-abstraction prevails over α-cleavage i

H-abstraction prevails over α-cleavage in the solution and solid state photochemistry of cis-2,6-di(1-cyclohexenyl)cyclohexanone

✍ Christopher J. Mortko; Hung Dang; Luis M. Campos; Miguel A. Garcı́a-Garibay 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 163 KB

The photochemistry of cis-2,6-di(1-cyclohexenyl)cyclohexanone was studied in solution and in crystals to determine its photoreactivity and chemoselectivity. Although 1,3-acyl shifts and the oxadi-p-methane rearrangement products are possible for the b,g-unsaturated chromophore, an efficient intramol

Photochemistry of 11,12-bis(Aminomethyl)

Photochemistry of 11,12-bis(Aminomethyl)-9,10-dihydro-9,10-ethenoanthracene in Solution and in the Solid State

✍ Scheffer, John R. ;Ihmels, Heiko 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 513 KB

## Abstract The photochemistry of 11,12‐bis(aminomethyl)‐9,10‐dihydro‐9,10‐ethenoanthracene (4) was investigated in solution and in the solid state. Direct irradiation of 4 gave the singlet state photoproduct 5, whereas the triplet derived photoproduct could only be obtained by irradiating the bis(