The new ligands 4Ј-nitro-2,2Ј:6Ј,2ЈЈ-terpyridine and 4Ј-prepared and the electrochemistry of the complexes has been investigated. amino-2,2Ј:6Ј,2ЈЈ-terpyridine and their homoleptic and heteroleptic iron(II) and ruthenium(II) complexes have been 2,2Ј:6Ј,2ЈЈ-Terpyridine (tpy) is a versatile ligand for
Novel didentate 2,2′:6′,2″-terpyridine complexes of ruthenium(II)
✍ Scribed by Edwin C. Constable; Alexander M.W. Cargill Thompson
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 281 KB
- Volume
- 223
- Category
- Article
- ISSN
- 0020-1693
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## Abstract A new series of dendrimers was assembled through formation of homo‐ and heteroleptic Ru^II^ complexes with [2,2′: 6′,2″]terpyridine ligands bearing hydrophilic and hydrophobic dendrons, with the aim to develop amphiphilic vectors for potential use in gene delivery (__Scheme 1__). The sy
## Abstract Routes for the syntheses of isomeric, zwitterionic, bisterpyridine–Ru^II^‐based macromolecules are described. Access to these novel architectures is facilitated by the construction of terpyridine‐modified, 1→3 __C__‐branched, ester‐terminated building blocks. Constitutional isomers resu