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Novel diamagnetic and paramagnetic iron(II), iron(III), and iron(IV) classical and nonclassical hyrides. X-ray crystal structure of [Fe(C5Me5)(dppe)D]PF6

✍ Scribed by Hamon, Paul; Toupet, Loic; Hamon, Jean Rene; Lapinte, Claude


Book ID
118127780
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
385 KB
Volume
11
Category
Article
ISSN
0276-7333

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Classical and non-classical iron hydride
✍ Jean-René Hamon; Paul Hamon; Loïc Toupet; Karine Costuas; Jean-Yves Saillard 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 192 KB

Protonation of Cp\*Fe(dppe)H (1; Cp\* = η 5 -C 5 Me 5 , dppe = Ph 2 PCH 2 CH 2 PPh 2 ) by HBF 4 Et 2 O at -80 °C in diethylether affords the dihydrogen complex [Cp\*Fe(dppe)(η 2 -H 2 )] + BF 4 -(2 + BF 4 -) in 90% yield. Its PF 6 -salt analogue (2 + PF 6 -) is obtained in 94% yield by reaction betwe