Rhodium and Iridium Ξ²-Diiminate Complexe
β
Peter H. M. Budzelaar; Nicolle N. P. Moonen; René de Gelder; Jan M. M. Smits; An
π
Article
π
2000
π
John Wiley and Sons
π
English
β 738 KB
The bulky Ξ²-diiminate ligands [(2,6-C 6 H 3 X 2 )NC(Me)CHC(-Me)N(2,6-C 6 H 3 X 2 )] -(X = Me, L Me ; X = Cl, L Cl ) have been found to be effective in stabilizing low coordination numbers (CN) in Rh and Ir complexes. The 14-e complex L Me Rh(COE) (COE = cyclooctene) has a three-coordinate T-shaped R