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Novel complexes of calcium with benzo-15-crown-5

✍ Scribed by N.S. Poonia; V.W. Bhagwat; S.K. Sarad


Publisher
Elsevier Science
Year
1977
Weight
181 KB
Volume
13
Category
Article
ISSN
0020-1650

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Complexes between the heavier lanthanoid nitrates Ln(NO~3~)~3~ and 15‐crown‐5 (**1**) and 18‐crown‐6 (**2**) ethers were isolated and characterized. Both 1:1 and 4:3 complexes are formed with each Ln(III) ion, except in the case of Gd and **2**. The thermal transformation of the 1:1 complexes into t