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Novel chemosensor for alkaline earth metal ion based on 9-anthryl aromatic amide using a naphthalene as a TICT control site and intramolecular energy transfer donor

✍ Scribed by Jeongsik Kim; Tatsuya Morozumi; Namiko Kurumatani; Hiroshi Nakamura


Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
338 KB
Volume
49
Category
Article
ISSN
0040-4039

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✦ Synopsis


Novel fluorescent chemosensors 1 and 2 with two different fluorophores (naphthalene and anthracene) at the both ends of polyether was synthesized. These compounds based on 9-anthryl aromatic amide adopted a naphthalene as a TICT controller and an intramolecular energy transfer source. Compound 1 shows high fluorescence efficiency upon complexation with metal ion, and the fluorescence efficiency of 2 is regulated by metal ionic size.