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Novel chemoselective de-esterification of esters of polyacetoxy aromatic acids by lipases

✍ Scribed by Virinder S. Parmar; Ajay Kumar; Kirpal S. Bisht; Shubhasish Mukherjee; Ashok K. Prasad; Sunil K. Sharma; Jesper Wengel; Carl E. Olsen

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
846 KB
Volume
53
Category
Article
ISSN
0040-4020

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✦ Synopsis

Candida cylindracea lipase (CCL) and porcine pancreatic lipase (PPL) have been used for deacetylation of peracetstes of methyl and ethyl esters of six different polyphenolic acids in organic solvents. Exclusive de-estefification of the ester groups derived from the phenolic hydroxy and aliphatic acid over the ester group of the aromatic acid and aliphatic alcohol has been achieved affording the corresponding esters of phenolic acids in as high yields as 90-97%. The results have been corroborated with the mechanism of lipase action.

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