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Novel catalysts for an alternating-type copolymerization by butadiene and acrylonitrile

✍ Scribed by Taniguchi, Masanobu ;Kawasaki, Akihiro ;Furukawa, Junji


Publisher
Wiley (John Wiley & Sons)
Year
1970
Tongue
English
Weight
21 KB
Volume
8
Category
Article
ISSN
0449-2986

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πŸ“œ SIMILAR VOLUMES


Alternating copolymer of butadiene and e
✍ Furukawa, Junji ;Hirai, Ryuichi πŸ“‚ Article πŸ“… 1972 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 451 KB

## Abstract Alternating copolymerization of butadiene and ethylene was investigated by the TiCl~4~βˆ’R~3~Al system as catalyst with the use of toluene solutions of monomers of various compositions or by introducing a 1:1 gaseous mixture of both monomers into the reaction system. It was found that the

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## Abstract **Summary:** By a sidearm approach, a series of titanium complexes bearing an [O, N, S] tridentate ligand have been synthesized and proven to be highly active for ethylene polymerization. The complexes also show excellent ability to copolymerize ethylene with hex‐1‐ene and norbornene. T