Novel catalysts for an alternating-type copolymerization by butadiene and acrylonitrile
β Scribed by Taniguchi, Masanobu ;Kawasaki, Akihiro ;Furukawa, Junji
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1970
- Tongue
- English
- Weight
- 21 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0449-2986
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π SIMILAR VOLUMES
## Abstract Alternating copolymerization of butadiene and ethylene was investigated by the TiCl~4~βR~3~Al system as catalyst with the use of toluene solutions of monomers of various compositions or by introducing a 1:1 gaseous mixture of both monomers into the reaction system. It was found that the
## Abstract **Summary:** By a sidearm approach, a series of titanium complexes bearing an [O, N, S] tridentate ligand have been synthesized and proven to be highly active for ethylene polymerization. The complexes also show excellent ability to copolymerize ethylene with hexβ1βene and norbornene. T