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Novel C2-Symmetric 1,1′-Disubstituted Ferrocenyl Aziridino Alcohol Ligands: Remarkable Improvement of Enantioselectivity in the Catalytic Asymmetric Addition of Diethylzinc to Aldehydes.

✍ Scribed by Min-Can Wang; Xue-Hui Hou; Cui-Lian Xu; Lan-Tao Liu; Gui-Lan Li; De-Kun Wang


Publisher
John Wiley and Sons
Year
2006
Weight
32 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Several new chiral auxiliaries with differing steric and electronic environments, such as ␣,␣Ј-dimethyl-2,6-pyridinedimethanol, ␣,␣Ј-ditrifluoromethyl-2,6pyridinedimethanol, ␣,␣Ј-dipentafluoroethyl-2,6-pyridinedimethanol, and ␣,␣Ј-diallyl-2,6pyridinedimethanol, have been examined and compared with ␣