✦ LIBER ✦

Novel Bulky Esters of Cellulose

✍ Scribed by Thomas Heinze; Matthias Pohl; Jens Schaller; Frank Meister

Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 173 KB
Volume: 7
Category: Article
ISSN: 1616-5187
DOI: 10.1002/mabi.200700103

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Novel bulky esters of cellulose were synthesized homogeneously, applying the solvent systems DMA/LiCl or DMSO/TBAF, by conversion of the biopolymer with aryl polyester dendrons. The carboxylic acid moieties were efficiently activated in situ with CDI or the acid chloride was applied. Cellulose esters with DS values of up to 0.7 were obtained. The functionalization pattern was analyzed by different NMR spectroscopic techniques indicating that not only position 6 (primary hydroxyl group) but also the secondary one at position 2 was included in the reaction.

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