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Novel Binuclear Phosphinidene Compounds by Dimerization of the PH-Functional Phosphenium Complexes [C5R5(CO)2WPH(Mes)] (R = H, Me)

✍ Scribed by Prof. Dr. Wolfgang Malisch; Dr. Ulrich-Andreas Hirth; Dr. Theresa A. Bright; Dr. Harald Käb; Dr. Teja Sebastian Ertel; Dipl.-Chem. Sabine Hückmann; Prof. Dr. Helmut Bertagnolli

Book ID
101557535
Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
389 KB
Volume
31
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES

Reactivity of the Inversely Polarised Ar
Reactivity of the Inversely Polarised Arsaalkenes R–As=C(NMe2)2 {R = [(η5-C5Me5)(CO)2Fe], tBuC(O)} Towards Vinylidene Complexes [η5-(C5H5)(CO)(NO)W=C=C(H)R] (R = Ph, tBu)
✍ Lothar Weber; Philipp Bayer; Gabriel Noveski; Hans-Georg Stammler; Beate Neumann 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 177 KB

## Abstract The reaction of the vinylidene complexes [(C~5~H~5~)(CO)(NO)W=C=C(H)R] (10a: R = __t__Bu; 10b: R = Ph) with the arsaalkene __t__BuC(O)–As=C(NMe~2~)~2~ (11) afforded the novel η^2^‐1‐arsaallene complexes [η^2^‐{__t__BuC(O)–As=C=C(H)R}W(CO)(NO)C~5~H~5~] (13: R = __t__Bu; 15: R = Ph). Simi