✦ LIBER ✦
Novel binding mode for fluorinated porphyrins: synthesis and fluorophilic affinity of stable atropoisomers of 5,10,15,20-tetrakis[2-(perfluoroacyl)aminophenyl]-21H,23H-porphyrins
✍ Scribed by Oldřich Paleta; Michal Beneš; Jitka Koutnı́ková; Vladimı́r Král
- Book ID
- 104251838
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- French
- Weight
- 162 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The synthesis and binding properties of 5,10,15,20-tetrakis[2-(perfluoroacyl)aminophenyl]-21H,23H-porphyrins as new types of fluorophilic receptors for potential application as optical sensors are reported. The observed remarkable binding affinity for fluorinated substrates monitored by vis spectroscopy represents a novel binding mode in porphyrin chemistry.