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Novel BF3OEt2/R−OH Initiating System for Controlled Cationic Polymerization of Styrene in the Presence of Water

✍ Scribed by Satoh, Kotaro; Nakashima, Junko; Kamigaito, Masami; Sawamoto, Mitsuo

Book ID
115467197
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
214 KB
Volume
34
Category
Article
ISSN
0024-9297

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Living cationic polymerization of styren
Living cationic polymerization of styrene by the bifunctional initiating system 1,4-bis(1-chloroethyl)benzene/SnCl4 in the presence of 2,6-di-tert-butylpyridine
✍ Oh-Sig Kwon; Chang Gi Gho; Byong-Seok Choi; Sam-Kwon Choi 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 393 KB

## Abstract The polymerization of styrene was studied by using a bifunctional initiator, 1,4‐bis(1‐chloroethyl)benzene (1). It was demonstrated that living polymerization can be achieved in the styrene/1/SnCl~4~ system in chloroform at −15°C in the presence of 2,6‐di‐__tert__‐butylpyridine. The num