Novel BEDT-TTF salts containing rare earth ions, (ET)4Ln(NCS)6·CH2Cl2

New Molecular Charge Transfer Salts of B

New Molecular Charge Transfer Salts of BEDT-TTF, Bis(ethylenedithio) Tetrathiafulvalene, with Thiocyanato-Complex Anions: (BEDT-TTF)4[Fe(NCS)6]·CH2Cl2 and (BEDT-TTF)2[Cr(NCS)4(bipym)]·0.15H2O

✍ Scott S. Turner; Peter Day; Thomas Gelbrich; Michael B. Hursthouse 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 341 KB

Two new charge transfer salts of BEDT-TTF, bis (ethylenedithio) tetrathiafulvalene, with thiocyanato-metal complex anions have been synthesized and characterized as (BEDT-TTF) 4 [Fe(NCS) 6 ] ' CH 2 Cl 2 and (BEDT-TTF) 2 [Cr(NCS) 4 (bipym)] ' 0.15H 2 O, where bipym ‫؍‬ 2,2-bipyrimidine. The Fe salt,