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Novel Barium Beryllates Ba[Be2N2] and Ba3[Be5O8]: Syntheses, Crystal Structures and Bonding Properties.

✍ Scribed by Stefano Leoni; Rainer Niewa; Lev Akselrud; Yurii Prots; Walter Schnelle; Tahsin Goeksu; Mehmet Cetinkol; Mehmet Somer; Ruediger Kniep


Publisher
John Wiley and Sons
Year
2005
Weight
10 KB
Volume
36
Category
Article
ISSN
0931-7597

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Systematic studies on quaternary thio-and selenoborates containing heavier alkaline earth metal cations led to the two new isotypic crystalline phases Sr 4.2 Ba 2.8 (BS 3 ) 4 S and Ba 7 (BSe 3 ) 4 Se. Both compounds consist of trigonal-planar BQ 3 (Q = S, Se) units, isolated Q 2Β± anions and the corr