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Novel [3 + 2] 1,3-Cycloaddition of the Ionized Carbonyl Ylide + CH 2 OCH 2• with Carbonyl Compounds in the Gas Phase

✍ Scribed by Eberlin, Marcos N.; Sorrilha, Ana Elisa P. M.; Gozzo, Fábio C.; Pimpim, Regina S.


Book ID
125901932
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
494 KB
Volume
119
Category
Article
ISSN
0002-7863

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Alkyl and alkylperoxy radicals originating from dimethyl ether have been studied in the gas phase at 296 K. A pulse radiolysis-UV absorption technique was used. Absorption cross-sections were quantified over the wavelength range 220-350 nm. At 230 nm, O'cH3oclJ2 = (4.2 + 0.5)× 10 -18 cm 2 molecule-l