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Nouvelle voie d'acces au squelette cyclopentenoidique

✍ Scribed by Thierry Herman; Rolf Carlson


Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
129 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis


A~E;yntheticmethodisproposedtop~racaniccyclopentenoicstructure~ with a chiral or pruSral center ti 2-trinkkhylsiloxy-2,3-butadiene _1.


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✍ P. Jost; P. Chaquin; J. Kossanyi πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 French βš– 129 KB

Irradiation of Z-allylcycloheptanone 3 forms a mixture of two oxetans, 4 and 2, in high yields. 11-Oxa tricycle 15.3.1 . 1'fO1 undecane 5, which constitutes The g/11 of the photoproducts, is decomposed thermally into a ?iiixture of hydroazulene derivatives. Dehydrogenation of this mixture over palla