𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Notizen/Notes Allenyl Enolates — A New Class of Chiral Ambident Nucleophiles, 2. Reaction with Iodine and Oxidizing Agents

✍ Scribed by Krause, Norbert ;Arndt, Silke


Publisher
Wiley (John Wiley & Sons)
Year
1993
Tongue
English
Weight
288 KB
Volume
126
Category
Article
ISSN
0009-2940

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Allenyl Enolates – A New Class of Chiral
✍ Becker, Markus ;Krause, Norbert 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 441 KB

## Abstract Allenic silyl ketene acetals 3 formed by conjugate 1,6‐addition of organocuprates to 2‐propen‐1‐yl and 2‐buten‐1‐yl 2‐en‐4‐ynoates 1 and regioselective enolate capture with silyl electrophiles readily undergo [3,3]‐Ireland‐Claisen rearrangements to the 2‐substituted methyl 3,4‐dienoates