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Notes - The Boiling Points of the Methylcyclohexanols-an Exception to the Conformational Rule

โœ Scribed by Eliel, Ernest; Haber, R


Book ID
126999441
Publisher
American Chemical Society
Year
1958
Tongue
English
Weight
263 KB
Volume
23
Category
Article
ISSN
0022-3263

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An Exception to the Hearsay Rule
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An exception to the CIDNP sign rules
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It is demonstrated experimentally that the CIDNP sign rules can give erroneous results. Net effects observed in the 'H NMR spectrum of I-phenyl[2-%]propan-2+ne after photolysis are correctly predicted at 360 MHz but not at 100 hlHz by the rules. The converse is true for the lH-13C multiplet effects.