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Notes- Synthesis of Benzyl Vinylcabamate and 3-O-Vinylcarbamoyl-D-mannitol Pentanitrate

โœ Scribed by Wolfrom, M; McFadden, G; Chaney, Alan


Book ID
121359656
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
399 KB
Volume
26
Category
Article
ISSN
0022-3263

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Synthesis of methyl 2-O-allyl-(and 3-O-a
โœ Trupti Desai; Jill Gigg; Roy Gigg ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 764 KB

D-Ribose was converted into methyl 5-O-benzyl-beta-D-ribofuranoside and this, on tin-mediated allylation, gave a mixture of the 2-O-allyl and 3-O-allyl derivatives which were separated by chromatography. The more polar isomer was characterised as the 3-O-allyl derivative after conversion via 3-O-all